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" dZ@  @" `  n?" dZ(@   @@``PR    @ ` ` p>  >   H @  (  8 t<  <t    B-CDEF1))?,0, @t<    BYC1DEFt1))?+0-0X @t<m   B-CDEF1))?,0,, @<    BYC1DEFo 1))?X0-+0X0 @t ~  Ni @1?p  Zxaxa1 ?H  ? Slide Title  #   TLxaxa1 ?q  ;Body Text Second Level Third Level Fourth Level Fifth Level     <   Txaxa1?Y@ F*    6-1?" VD Gallagher, CAChe Group, 1999 2 B  s *޽h ? qD=i( Default Design0 WO`( Ho{( #  T@gg1 ? L!  ;Body Text Second Level Third Level Fourth Level Fifth Level     <  TZZ1? e  Page *Z ---CCYYp  01 ?MC  B  s *jB ? a(80___PPT10.PUv  (  ?  <  Z-eݲeݲ1?/O  `Color Chemistry  David Gallagher  2 March 200411AAAaa   `\teݲeݲ1?   rColor Chemistry ,AAAaa  Td-eݲeݲ t - z Page *,  AAAaaB  s *jB ? a(80___PPT10.    .;P^(    3 r-xaxa1 ?HS   f8 n<k +<nk@ | "a  kZB   s *Dp?Z"ZB   s *D8c?TZB   s *D8c?Z, ", ZB  s *D8c?TT T ZB  s *D8c?N| |   H01?AIa JS0, N | "a  n<! ZB  s *Dp?Z"ZB  s *D8c?TZB  s *D8c?Z, ", ZB  s *D8c?TT T ZB  s *D8c?N| |   HT61?AIa JS1, dB  <DԔ?  dB  <D1? dB  <D1?..  4 HH;1? 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Np1?  .Fluorescence*  ~ 535nm@ d / C <A$fluorescein(EtOH)4Z l 0 C DA,fluorescein-S1-(EtOH)  l %2 < 92 %<,$D0t 8 68c?"`82 <@ %: & 5%8 &n 1 c >Afluorescence: & 2 <L1?%h V g-Calculated Absorption & Fluorescence Spectra..z 3 C RA:fluorescein-dibase-structure# N 4 HЍ1?  Y fluorescein2-0  7 <1?~ D*H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design and research tool in photochemistry," Photochemistry and Photobiology, 68, 141-142, 1998  P  tH  0޽h ? qD=i(~___PPT10^+IDB' = @B D' = @BA?%,( < +O%,( < +D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*9%(+   @0b(  P 0 C (Afluor-23  / H(1?"`; =,$D0 6Fluorescence Emission Property of:  excited states Property:  optimized geometry Using:  PM3/CI........geometry Property of:  chemical sample Property:  UV-visible transitions Using:  current geometry ` x @`  3 rxaxa1 ?HS     ) Hp1?"`;J  UV-visible Absorption Property of:  chemical sample Property:  UV-visible transitions Using:  ZINDO CI at PM3 geo... ` b x c @`H  0޽h ? qD=i(___PPT10+1ydDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*/%(+8+0+/0 +H0 e]P(  d  c $MC   Q  s * L!   The band width can be estimated from the gradient of the excited state at the minimum energy geometry of the ground state. At a high gradient, the ground state can overlap with a wide range of vibration levels (blue line). At a low gradient, the ground state overlaps with only a few vibrational levels. The gradient can be calculated by running a single energy point excited state calculation on the ground state geometry. H  0jB ? a(I0 e](  d  c $MC   -Q  s *0- L!  - The band width can be estimated from the gradient of the excited state at the minimum energy geometry of the ground state. At a high gradient, the ground state can overlap with a wide range of vibration levels (blue line). At a low gradient, the ground state overlaps with only a few vibrational levels. The gradient can be calculated by running a single energy point excited state calculation on the ground state geometry. H  0jB ? a(J0 e]p(  d  c $MC   -Q  s *lz- L!  - The band width can be estimated from the gradient of the excited state at the minimum energy geometry of the ground state. At a high gradient, the ground state can overlap with a wide range of vibration levels (blue line). At a low gradient, the ground state overlaps with only a few vibrational levels. The gradient can be calculated by running a single energy point excited state calculation on the ground state geometry. 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